论文标题
泰坦条件下乙烯蒸发岩的实验研究
Experimental Study of Ethylene Evaporites under Titan Conditions
论文作者
论文摘要
卡西尼(Cassini)证实,泰坦(Titan)有大量的湖泊和海洋。这些液体的主要成分包括甲烷($ ch_4 $)和乙烷($ C_2H_6 $);但是,有证据表明,湖泊中也可能存在诸如乙烯($ C_2H_4 $)之类的次要组成部分。随着湖泊水平下降,落在地球上的5 $ $ $ abright沉积物(类似于蒸发物沉积物)被留在后面。在这里,我们通过使用能够再现泰坦表面条件的泰坦模拟室(89-94 K,1.5 bar $ n_2 $)来提供饱和值,蒸发速率和对乙烯蒸发形成的限制。使用傅立叶变换红外光谱,质量和温度读数分析实验样品。在甲烷溶剂中比在乙烷溶剂或甲烷/乙烷的混合物中更快地形成乙烯。我们测量的平均蒸发率为$(2.8 \ pm 0.3)\ times 10^{ - 4} kg \; m^{ - 2} \;甲烷的s^{ - 1} $,平均上限蒸发率小于$ 5.5 \ times 10^{ - 6} kg \; m^{ - 2} \; S^{ - 1} $用于Ethane。此外,我们观察到1.630和2.121 $μm$的乙烯吸收带的红移,以及1.666 $μm$的甲烷带的持久性。
Titan has an abundance of lakes and seas, as confirmed by Cassini. Major components of these liquid bodies include methane ($CH_4$) and ethane ($C_2H_6$); however, evidence indicates that minor components such as ethylene ($C_2H_4$) may also exist in the lakes. As the lake levels drop, 5 $μm$-bright deposits, resembling evaporite deposits on earth, are left behind. Here, we provide saturation values, evaporation rates, and constraints on ethylene evaporite formation by using a Titan simulation chamber capable of reproducing Titan surface conditions (89-94 K, 1.5 bar $N_2$). Experimental samples were analyzed using Fourier transform infrared spectroscopy, mass, and temperature readings. Ethylene evaporites form more quickly in a methane solvent than in an ethane solvent or in a mixture of methane/ethane. We measured an average evaporation rate of $(2.8 \pm 0.3) \times 10^{-4} kg \; m^{-2} \; s^{-1}$ for methane and an average upper limit evaporation rate of less than $5.5 \times 10^{-6} kg \; m^{-2} \; s^{-1}$ for ethane. Additionally, we observed red shifts in ethylene absorption bands at 1.630 and 2.121 $μm$ and the persistence of a methane band at 1.666 $μm$.