论文标题

翻译冷的CCL+反应与乙炔(C2H2)

Translationally cold trapped CCl+ reactions with acetylene (C2H2)

论文作者

Catani, Katherine J., Greenberg, James, Saarel, Benjamin V., Lewandowski, Heather J.

论文摘要

离子中性化学反应在化学的多个领域很重要,包括星际培养基的某些区域,行星大气和彗星。测量了CCL+与C2H2的反应,主要产品包括C-C3H2+和L-C3H+,均与外星环境有关。获得准确的分支比率,有利于形成C-C3H2+超过L-C3H+的四倍。测得的速率常数在langevin的顺序上,互补的电子结构计算用于帮助解释实验结果。

Ion-neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured and the main products include c-C3H2+ and l-C3H+, both relevant in extraterrestrial environments. Accurate branching ratios are obtained, which favor formation of c-C3H2+ over l-C3H+ by a factor of four. Measured rate constants are on the order of Langevin and complementary electronic structure calculations are used to aid in the interpretation of experimental results.

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