论文标题

用于变形导体和电磁干扰屏蔽的石墨烯 - 丙烷涂层

Graphene-Polyurethane Coatings for Deformable Conductors and Electromagnetic Interference Shielding

论文作者

Cataldi, Pietro, Papageorgiou, Dimitrios G., Pinter, Gergo, Kretinin, Andrey V., Sampson, William W., Young, Robert J., Bissett, Mark, Kinloch, Ian A.

论文摘要

即使在执行重大的机械变形下,执行电极的电导性聚合物材料,执行电极,符合的电磁屏蔽,可拉伸的触觉传感器和柔性能量存储。这些材料面临的挑战在于,即使在低应变下,渗透的,导电网络也倾向于分离,从而导致重大压力。在此,通过用石墨烯 - 弹性溶液喷涂氮气底物来制造可变形的导体。涂料仅在数千个弯曲周期和反复折叠事件后仅显示出电阻的略有增加。可变形的导体在12%应变下将其电阻翻了一番,并且在不改变其电性能的情况下可洗。通过考虑变形后的纳米分离来对电导率 - 应变行为进行建模。为了提高较高应变的电导率,通过在喷涂之前拉伸硝酸基底物来调整生产过程,之后释放出来。这种适应意味着电阻在25%应变时翻了一番。发现电阻足够低,以在8-12 GHz电磁条带中屏蔽1.9 dB/μm。发现弹性导体的物理和电气特性,包括EM筛选,在循环时会恶化,但可以通过重新加热涂层来恢复。

Electrically conductive, polymeric materials that maintain their conductivity even when under significant mechanical deformation are needed for actuator electrodes, conformable electromagnetic shielding, stretchable tactile sensors and flexible energy storage. The challenge for these materials is that the percolated, electrically conductive networks tend to separate even at low strains, leading to significant piezoresistance. Herein, deformable conductors were fabricated by spray-coating a nitrile substrate with a graphene-elastomer solution. The coatings showed only slight increase in electrical resistance after thousands of bending cycles and repeated folding-unfolding events. The deformable conductors doubled their electrical resistance at 12% strain and were washable without changing their electrical properties. The conductivity-strain behaviour was modelled by considering the nanofiller separation upon deformation. To boost the conductivity at higher strains, the production process was adapted by stretching the nitrile substrate before spraying, after which it was released. This adaption meant that the electrical resistance doubled at 25 % strain. The electrical resistance was found sufficiently low to give a 1.9 dB/μm shielding in the 8-12 GHz electromagnetic band. The physical and electrical properties, including the EM screening, of the flexible conductors, were found to deteriorate upon cycling but could be recovered through reheating the coating.

扫码加入交流群

加入微信交流群

微信交流群二维码

扫码加入学术交流群,获取更多资源