论文标题
湍流中的聚合物分裂
Polymer scission in turbulent flows
论文作者
论文摘要
湍流中的聚合物会受到严重的应变,这可能会导致其细胞,从而限制了现象的实验研究和应用,例如湍流阻力减少和弹性湍流。在本文中,我们通过基于高斯时间与时间相关的随机流以及直接的数值模拟(DNSS)以及单向(被动)和单向(被动)和双向(主动)(主动)和流动的直接数值模拟(DNSS)来研究均质各向同性湍流中的聚合物分裂。对于被动聚合物的首次分割,随机模型产生的分析预测与DNSS的结果非常吻合,对于不间断聚合物的分数和聚合物生存的统计数据的时间演变。通过具有双向耦合(活性聚合物)的DNSS研究了Scission对湍流聚合物溶液动力学的影响。我们的结果表明,由于拉伸聚合物的反馈而导致的动能消散是一种固有的瞬态效应,它随着聚合物的破裂而丢失。因此,通过中间聚合物弛豫时间最大化了总体耗散量的减少,为此,聚合物会显着延伸,但不会太快破裂。我们还研究了分裂后形成的聚合物片段的动力学。这些女儿聚合物本身可以随后重复分解,以产生分层的聚合物,这些聚合物具有一系列放松时间和分裂率。
Polymers in a turbulent flow are subject to intense strain, which can cause their scission and thereby limit the experimental study and application of phenomena such as turbulent drag reduction and elastic turbulence. In this paper, we study polymer scission in homogeneous isotropic turbulence, through a combination of stochastic modelling, based on a Gaussian time-decorrelated random flow, and direct numerical simulations (DNSs) with both one-way (passive) and two-way (active) coupling of the polymers and the flow. For the first scission of passive polymers, the stochastic model yields analytical predictions which are found to be in good agreement with results from the DNSs, for the temporal evolution of the fraction of unbroken polymers and the statistics of the survival of polymers. The impact of scission on the dynamics of a turbulent polymer solution is investigated through DNSs with two-way coupling (active polymers). Our results indicate that the reduction of kinetic energy dissipation due to feedback from stretched polymers is an inherently transient effect, which is lost as the polymers breakup. Thus, the overall dissipation-reduction is maximised by an intermediate polymer relaxation time, for which polymers stretch significantly but without breaking too quickly. We also study the dynamics of the polymer fragments which form after scission; these daughter polymers can themselves undergo subsequent, repeated, breakups to produce a hierarchical population of polymers with a range of relaxation times and scission rates.