论文标题
电子分子中电子与宇宙场的平均不连接相互作用
Parity nonconserving interactions of electrons in chiral molecules with cosmic fields
论文作者
论文摘要
伪内科或伪cosmic领域,它们是违规的均等来源($ \ Mathcal {p} $),在不同的模型中用于冷暗物质或标准模型扩展中,该模型允许违反Lorentz的不变性。直接检测到此类字段的时间表组件需要直接测量$ \ Mathcal {p} $ - 奇数势或它们随时间的演变。在此,手性分子的优势性能,其中$ \ Mathcal {p} $ - 奇数可能导致对映异构体之间的共振频率差异,以直接检测到这种$ \ Mathcal {p} $ - 奇数宇宙宇宙领域。电子结构相对于核电荷数和细胞结构常数的扩展的扩展行为是分析得出的。这可以简单地估算任意分子的效果大小。分析推导由分子H $ _2 $ X $ _2 $和H $ _2 $ XO的分子数值计算支持,x $ = $ = $ o,s,s,se,te,po。将由于CHBRCLF中C-F拉伸模式的宇宙域而违反均衡效应与Electroweak Price违规和不可分割的Anharmonic振动校正的影响进行了比较。在此基础上,它是根据二十年历史的CHBRCLF实验估计的,该实验是由Lorentz不变性违规的范围,其特征是参数$ | b^\ Mathrm {e} _0 | $可以将其推向$ 10^{ - 17} \,\ Mathrm {geev,\ Mathrm {geev,\ mathrm {geev,\ nathrm {geev,\ nathrm {至少有两个数量级。这有助于强调手性分子精确光谱在搜索标准模型以外的新物理学时提供的特定机会。
Pseudoscalar or pseudovector cosmic fields, that serve as a source of parity ($\mathcal{P}$) violation, are invoked in different models for cold dark matter or in the standard model extension that allows for Lorentz invariance violation. A direct detection of the timelike-component of such fields requires a direct measurement of $\mathcal{P}$-odd potentials or their evolution over time. Herein, advantageous properties of chiral molecules, in which $\mathcal{P}$-odd potentials lead to resonance frequency differences between enantiomers, for direct detection of such $\mathcal{P}$-odd cosmic fields are demonstrated. Scaling behavior of electronic structure enhancements of such interactions with respect to nuclear charge number and the fine-structure constant is derived analytically. This allows a simple estimate of the effect sizes for arbitrary molecules. The analytical derivation is supported by quasi-relativistic numerical calculations in the molecules H$_2$X$_2$ and H$_2$XO with X $=$ O, S, Se, Te, Po. Parity violating effects due to cosmic fields on the C--F stretching mode in CHBrClF are compared to electroweak parity violation and influences of non-separable anharmonic vibrational corrections are discussed. On this basis it was estimated from a twenty year old experiment with CHBrClF that bounds on Lorentz invariance violation as characterized by the parameter $|b^\mathrm{e}_0|$ can be pushed down to the order of $10^{-17}\,\mathrm{GeV}$ in modern experiments with suitably selected molecular system, which will be an improvement of the current best limits by at least two orders of magnitude. This serves to highlight the particular opportunities that precision spectroscopy of chiral molecules provides in the search for new physics beyond the standard model.