论文标题

新的金属间CE $ _2 $ rh $ _2 $ ga的两个多晶型物 - 晶体结构和物理特性

Two polymorphs of a new intermetallic Ce$_2$Rh$_2$Ga -- crystal structure and physical properties

论文作者

Nesterenko, Sergey, Tursina, Anna, Pasturel, Mathieu, Xhakaza, Sindisiwe, Strydom, André

论文摘要

我们报告了新三元金属间CE $ _2 $ rh $ _2 $ ga的合成和物理属性。已经通过粉末和单晶X射线衍射法以及差分热分析研究了其形成和二态性。 LT-和HT-CE $ _2 $ RH $ _2 $ ga可以通过所选的热处理获得。高温形式(ht-ce $ _2 $ rh $ _2 $ ga),稳定在864(5)°C以上的稳定性,是正常的LA2NI3-type [CMCE,OS20,A = 5.851(2)(2)Å,B = 9.618(2)Å,C = 9.618(2)Å,C = 7.487(2)Å3(2)(2)(2)(2)(2)(2)(2)(2)(2)(2)(2)(2)(2)Å,V = 42(2) the low-temperature form (LT-Ce$_2$Rh$_2$Ga), stable below this temperature, is monoclinic Pr2Co2Al- (Ca2Ir2Si-) type [C2/c, mS20, a=10.0903(6) A, b=5.6041(3) A, c=7.8153(4) A, beta=104.995(3) degrees, V = 426.88(4)A3]。磁性测量是在两个不同的样本上进行的,即LT-CE $ _2 $ RH $ _2 $ GA,另一个在HT-CE $ _2 $ RH $ _2 $ _2 $ GA样本上进行。 HT-CE $ _2 $ RH $ _2 $ ga化合物被发现在128.5 K.的相过渡时,由于磁敏感性的温度依赖性在温度下的尖峰异常,这种相变的起源可能是反铁磁起源的,但与CE型和Ternary ternary ternary ternary ternary是典型的温度相比,其温度非常高。 lt- ce $ _2 $ rh $ _2 $ gaa具有铁磁性质的基础状态,该状态以5.2 k的顺磁性向有限磁相变的位置。

We report on the synthesis and physical properties of the new ternary intermetallic Ce$_2$Rh$_2$Ga. Its formation and dimorphism have been investigated by powder and single crystal X-ray diffractometry, as well as by differential thermal analyses. LT- and HT-Ce$_2$Rh$_2$Ga can be obtained by the chosen respective thermal treatment. The high-temperature form (HT-Ce$_2$Rh$_2$Ga), stable above 864(5)°C, is orthorhombic La2Ni3-type [Cmce, oS20, a=5.851(2) Å, b=9.618 (2) Å, c=7.487 (2) Å, V=421.3(2) Å3]; the low-temperature form (LT-Ce$_2$Rh$_2$Ga), stable below this temperature, is monoclinic Pr2Co2Al- (Ca2Ir2Si-) type [C2/c, mS20, a=10.0903(6) A, b=5.6041(3) A, c=7.8153(4) A, beta=104.995(3) degrees, V=426.88(4) A3]. The magnetic measurements were conducted on two different samples, namely on the LT-Ce$_2$Rh$_2$Ga and the other on the HT-Ce$_2$Rh$_2$Ga sample. The HT-Ce$_2$Rh$_2$Ga compound is found to exhibit a phase transition at 128.5 K. By virtue of the sharp peak anomaly in the temperature dependence of the magnetic susceptibility this phase transition is plausibly of antiferromagnetic origin, but occurs at a remarkably high temperature compared to what is typical for Ce binary and ternary compounds. LT- Ce$_2$Rh$_2$Gaa has a ground state of ferromagnetic nature which sets in at a paramagnetic-to-ferromagnetic phase transition at 5.2 K.

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