论文标题

伴随热波动的间歇性重排将眼镜与晶体区分开

Intermittent rearrangements accompanying thermal fluctuations distinguish glasses from crystals

论文作者

Mizuno, Hideyuki, Tong, Hua, Ikeda, Atsushi, Mossa, Stefano

论文摘要

在凝聚的物理学中,玻璃表现出与晶体明显不同的振动和热特性,这是一个持久的问题。尽管最近的作品使我们对谐波近似限制的眼镜中振动激发的理解提高了我们的理解,但了解有限温度的非谐波过程的努力受到限制。众所周知,晶体中的声子通过声子 - 语音相互作用,这是一种极有效的非谐衰减机制,在玻璃杯中也很重要。但是,在这里,我们表明,在玻璃杯的情况下,出现了另一个不同来源的额外的非谐道通道,该通道会导致颗粒的间歇性重排。我们发现,玻璃中的热振动触发了许多不同局部能量景观的最小值的过渡,但是,该景观位于同一宽(元)盆地内。这些过程产生的动作与扩散和平衡的衰老动力学不同。我们建议,伴随热波动的间歇性重排是将玻璃与晶体区分开的关键特征。

It is a persistent problem in condensed matter physics that glasses exhibit vibrational and thermal properties that are markedly different from those of crystals. While recent works have advanced our understanding of vibrational excitations in glasses at the harmonic approximation limit, efforts in understanding finite-temperature anharmonic processes have been limited. It is well known that phonons in crystals couple through phonon-phonon interactions, an extremely efficient mechanism for anharmonic decay that is also important in glasses. Here, however, we show that an additional anharmonic channel of different origin emerges in the case of glasses, which induces intermittent rearrangements of particles. We have found that thermal vibrations in glasses trigger transitions among numerous different local minima of the energy landscape, which, however, are located within the same wide (meta)basin. These processes generate motions that are different from both diffusive and out-of-equilibrium aging dynamics. We suggest that the intermittent rearrangements accompanying thermal fluctuations are crucial features distinguishing glasses from crystals.

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