论文标题
胶体凝胶化中的非平衡连续相变和短距离吸引力
Nonequilibrium continuous phase transition in colloidal gelation with short-range attraction
论文作者
论文摘要
有吸引力的胶体颗粒动态停滞在非平衡结构中,称为凝胶化,是生物物理学,材料科学,纳米技术以及食品和化妆品应用的核心,但缺乏完全的理解。特别是,对于中间粒子的密度和吸引力,结构形成过程尚不清楚。在这里,我们表明,短距离有吸引力的颗粒的凝胶由非平衡渗透过程控制。我们将临界Casimir胶体悬浮液,数值模拟和分析建模的实验与主动力学方程相结合,以表明群集大小和相关长度与指数分别与1.6和0.8的指数相差,而与渗透理论保持一致,而粒子的依恋和分离过程中的详细平衡则损坏了。群集质量在渗透前和之后具有指数-3/2和-5/2指数的幂律分布,这是通过对主动力学方程的解决方案所预测的。这些结果揭示了无等值的连续相变统一结构停滞,并屈服于相关框架。
The dynamical arrest of attractive colloidal particles into out-of-equilibrium structures, known as gelation, is central to biophysics, materials science, nanotechnology, and food and cosmetic applications, but a complete understanding is lacking. In particular, for intermediate particle density and attraction, the structure formation process remains unclear. Here, we show that the gelation of short-range attractive particles is governed by a nonequilibrium percolation process. We combine experiments on critical Casimir colloidal suspensions, numerical simulations, and analytical modeling with a master kinetic equation to show that cluster sizes and correlation lengths diverge with exponents 1.6 and 0.8, respectively, consistent with percolation theory, while detailed balance in the particle attachment and detachment processes is broken. Cluster masses exhibit power-law distributions with exponents -3/2 and -5/2 before and after percolation, as predicted by solutions to the master kinetic equation. These results revealing a nonequilibrium continuous phase transition unify the structural arrest and yielding into related frameworks.