论文标题

外部磁场中的远程磁顺序的破坏以及Cu2Gabo5和Cu2albo5 ludwigites中相关的自旋动力学

Destruction of long-range magnetic order in an external magnetic field and the associated spin dynamics in Cu2GaBO5 and Cu2AlBO5 ludwigites

论文作者

Kulbakov, A. A., Sarkar, R., Janson, O., Dengre, S., Weinhold, T., Moshkina, E. M., Portnichenko, P. Y., Luetkens, H., Yokaichiya, F., Sukhanov, A. S., Eremina, R. M., Schlender, Ph., Schneidewind, A., Klauss, H. -H., Inosov, D. S.

论文摘要

量子旋转系统Cu $ _2 $ M'bo $ _5 $(M'= Al,GA),其Ludwigite晶体结构由结构上有序的Cu $^{2+} $ sublattice组成,形式为三腿梯子的形式,由统计上的Sunterpynity sunterpentice intherpentionalline sublattice instryline Magnerticalline Magnitiontiment in Magnitiment in Magnitiment in Magnitigantiment $^2 ga $^{3+} $或al $^{3+} $ ions。基于Cu $ _2 $ GABO $ _5 $的密度功能理论计算的显微镜分析显示,一种令人沮丧的准二维旋转模型,具有五个不等于的反铁磁交换。宽阔的低温$^{11} $ b核磁共振指向系统中的旋转障碍。在零磁场中,抗磁磁序在$ t_ \ text {n} $ $ \ $ 4.1 k和〜2.4 k中分别为GA和AL化合物设置。从中子衍射中,我们发现Cu $ _2 $ gabo $ _5 $中的磁性传播向量是相称的,并且位于(H0L)飞机中的Brillouin-Zone边界上,$ \ MATHBF {q} _ \ text _ \ text {m} $ =(0.45 0 -0 0 -0.7),较大的序列,与复杂的序列相关的序列。 MUON自旋松弛是单调的,由复杂非连续性自旋系统的典型快速静态组件和一个缓慢的动态组件组成,该组件源自低能旋转波动的弛豫。非弹性中子散射也证明了以弥漫性准峰峰形式形式的无间隙自旋动力学。最值得注意的是,磁场在1 t上方的应用破坏了静态远程顺序,这表现在磁性bragg峰的逐渐扩大中。我们认为,这种从磁性长距离有序状态到旋转玻璃制度的交叉可能是由结构无序的磁性弹药上的孤儿旋转导致的,该磁​​性弹药在磁场中偏振,因此是场对控制的磁性障碍的调音旋钮。

The quantum spin systems Cu$_2$M'BO$_5$ (M' = Al, Ga) with the ludwigite crystal structure consist of a structurally ordered Cu$^{2+}$ sublattice in the form of three-leg ladders, interpenetrated by a structurally disordered sublattice with a statistically random site occupation by magnetic Cu$^{2+}$ and nonmagnetic Ga$^{3+}$ or Al$^{3+}$ ions. A microscopic analysis based on density-functional-theory calculations for Cu$_2$GaBO$_5$ reveals a frustrated quasi-two-dimensional spin model featuring five inequivalent antiferromagnetic exchanges. A broad low-temperature $^{11}$B nuclear magnetic resonance points to a considerable spin disorder in the system. In zero magnetic field, antiferromagnetic order sets in below $T_\text{N}$ $\approx$ 4.1 K and ~2.4 K for the Ga and Al compounds, respectively. From neutron diffraction, we find that the magnetic propagation vector in Cu$_2$GaBO$_5$ is commensurate and lies on the Brillouin-zone boundary in the (H0L) plane, $\mathbf{q}_\text{m}$ = (0.45 0 -0.7), corresponding to a complex noncollinear long-range ordered structure with a large magnetic unit cell. Muon spin relaxation is monotonic, consisting of a fast static component typical for complex noncollinear spin systems and a slow dynamic component originating from the relaxation on low-energy spin fluctuations. Gapless spin dynamics in the form of a diffuse quasielastic peak is also evidenced by inelastic neutron scattering. Most remarkably, application of a magnetic field above 1 T destroys the static long-range order, which is manifested in the gradual broadening of the magnetic Bragg peaks. We argue that such a crossover from a magnetically long-range ordered state to a spin-glass regime may result from orphan spins on the structurally disordered magnetic sublattice, which are polarized in magnetic field and thus act as a tuning knob for field-controlled magnetic disorder.

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