论文标题
基于PDMS的微流体约束中的时间依赖性溶作染色器纹理
Time dependent lyotropic chromonic textures in PDMS-based microfluidic confinements
论文作者
论文摘要
长期以来,已经研究了溶式染色体液体晶体(LCLC)的列表和柱状阶段,以研究其材料科学和医学诊断方面的基本和应用前景。 LCLC相代表椎间盘形分子的不同自组装状态,通过非共价相互作用,导致高度敏感的浓度和温度依赖性。然而,缺乏对限制LCLC的微观见解,特别是在限制几何和表面特性的背景下。在这里,我们报告了限制在基于PDMS的微流体设备中的静态disodium铬酸(DSCG)溶液中时间相关纹理的出现。 We use a combination of soft lithography, surface characterization and polarized optical imaging to generate and analyze the confinement-induced LCLC textures, and demonstrate that over time, herringbone and spherulite textures emerge due to spontaneous nematic (N) to columnar M-phase transition, propagating from the LCLC-PDMS interface into the LCLC bulk.通过改变限制几何形状,锚定条件和初始DSCG浓度,我们可以系统地调整n到M期转换的时间动力学和受限LCLC的质地行为。由于静态分子状态记录了LC流的初始条件,因此此处报告的时间依赖性边界和大量条件表明,局部表面介导的动力学可能是理解LCLC流动的核心,而又一次,此反过来又是该多功能材料的相关运输特性。
Nematic and columnar phases of lyotropic chromonic liquid crystals (LCLCs) have been long studied for their fundamental and applied prospects in material science and medical diagnostics. LCLC phases represent different self-assembled states of disc-shaped molecules, held together by noncovalent interactions that lead to highly sensitive concentration and temperature dependent properties. Yet, microscale insights into confined LCLCs, specifically in the context of confinement geometry and surface properties, are lacking. Here, we report the emergence of time dependent textures in static disodium chromoglycate (DSCG) solutions, confined in PDMS-based microfluidic devices. We use a combination of soft lithography, surface characterization and polarized optical imaging to generate and analyze the confinement-induced LCLC textures, and demonstrate that over time, herringbone and spherulite textures emerge due to spontaneous nematic (N) to columnar M-phase transition, propagating from the LCLC-PDMS interface into the LCLC bulk. By varying the confinement geometry, anchoring conditions and the initial DSCG concentration, we can systematically tune the temporal dynamics of the N to M-phase transition and textural behaviour of the confined LCLC. Since static molecular states register the initial conditions for LC flows, the time dependent boundary and bulk conditions reported here suggest that the local surface-mediated dynamics could be central in understanding LCLC flows, and in turn, the associated transport properties of this versatile material.