论文标题

直接测量可调节的半偏度铁电化

Direct measurement of ferroelectric polarization in a tunable semimetal

论文作者

de la Barrera, Sergio C., Cao, Qingrui, Gao, Yang, Gao, Yuan, Bheemarasetty, Vineetha S., Yan, Jiaqiang, Mandrus, David G., Zhu, Wenguang, Xiao, Di, Hunt, Benjamin M.

论文摘要

铁电性是铁磁性的静电对应物,长期以来一直被认为与金属性不兼容,这是由于电偶极子和外部电场通过巡回费用而引起的。然而,最近的测量结果表明,wte $ _2 $的双层电导和三层的电导率(一种半金属过渡金属二进制二色氏元素,反转对称性损坏)的签名。该系统的一个特别有希望的方面是,可以通过外栅极电压连续调节电子和孔的密度。这种自由度可以调查铁电和自由载体之间的相互作用,这是一个以前未开发的制度。在这里,我们在双层WTE $ _2 $的双门控介质设备中采用电容感应,以直接测量金属状态的自发极化,并分别量化游离载体对传导和价带中极化的影响。我们将结果与电子带的低能模型进行比较,并确定同时有助于运输和极化的层极化状态。因此,BiLayer WTE $ _2 $被证明是铁电金属的规范示例,也是探索极性有序,铁电跃迁和在自由载体存在下应用的理想平台。

Ferroelectricity, the electrostatic counterpart to ferromagnetism, has long been thought to be incompatible with metallicity due to screening of electric dipoles and external electric fields by itinerant charges. Recent measurements, however, demonstrated signatures of ferroelectric switching in the electrical conductance of bilayers and trilayers of WTe$_2$, a semimetallic transition metal dichalcogenide with broken inversion symmetry. An especially promising aspect of this system is that the density of electrons and holes can be continuously tuned by an external gate voltage. This degree of freedom enables investigation of the interplay between ferroelectricity and free carriers, a previously unexplored regime. Here, we employ capacitive sensing in dual-gated mesoscopic devices of bilayer WTe$_2$ to directly measure the spontaneous polarization in the metallic state and quantify the effect of free carriers on the polarization in the conduction and valence bands, separately. We compare our results to a low-energy model for the electronic bands and identify the layer-polarized states that contribute to transport and polarization simultaneously. Bilayer WTe$_2$ is thus shown to be a canonical example of a ferroelectric metal and an ideal platform for exploring polar ordering, ferroelectric transitions, and applications in the presence of free carriers.

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