论文标题
由于不变键长而导致的旋转分子气体振动热容量的电气脱离
Breakdown of equipartition of energy for vibrational heat capacity of diatomic molecular gas due to nonvanishing bond length
论文作者
论文摘要
当能量的平选定理适用于双原子分子气体内的振动自由度时，键长通常以零为零，以使定理有效。一旦考虑到键长，计算表明振动热容量的平均能量将显着偏离分解键的高温附近的标准值。
When the theorem of equipartition of energy applies to the vibrational degree of freedom within diatomic molecular gas, the bond length is usually taken as zero so that the theorem is valid. Once the bond length is taken into consideration, calculations show that the mean energy of the vibrational heat capacity will significantly deviate from the standard value near the high temperature which breaks down the bond.
