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We present the full next-to-leading-order electroweak and QCD corrections to vector-boson scattering into a pair of off-shell opposite-sign W bosons decaying into leptons of different flavour at the LHC. We include full leading-order predictions for the irreducible background. Explicitly, we investigate the process ${\rm pp \to e^+ ν_eμ^-\barν_μjj} + X$ at leading orders $O(α^6)$, $O(\rmα_sα^5)$, $O(\rmα_s^2α^4)$, supplemented by the loop-induced $O(\rmα_s^4α^4)$ contribution, and at next-to-leading orders $O(α^7)$ and $O(\rmα_sα^6)$ in two setups providing fiducial cross sections as well as differential distributions. We take full account of photon-induced next-to-leading-order contributions, which prove to be non negligible. With $-11.4\%$ and $-6.7\%$ in the two setups, the electroweak corrections are smaller than for other vector-boson-scattering processes. This can be traced back to the presence of the Higgs-boson resonance in the fiducial phase space, whose effects we analyse within an additional unphysical, but manifestly gauge-invariant setup. The QCD corrections amount to $-5.1\%$ and $-21.6\%$ in the two setups. The large size of the latter correction, compared to other vector-boson scattering processes, is explained by a very restrictive definition of its fiducial phase space.