论文标题
集中挫败感,以使柔性,弯曲的颗粒的自限制组装
Focussing frustration for self-limiting assembly of flexible, curved particles
论文作者
论文摘要
我们表明,在一系列可变形和自然弯曲的壳状胶体颗粒中的几何挫败感会导致有限大小的堆栈的自限制组装,这些堆栈远远超过了粒子的尺寸。当颗粒间粘附有利于共形堆叠时,颗粒形状需要堆栈中的{\ it曲率浓缩},从而导致弯曲成本的超扩张积累,最终将基础堆栈尺寸限制在有限的值中。使用连续理论和基于粒子的模拟的结合,我们证明了自限制的堆栈大小由粒子内弯曲成本与粒子间粘附能的比率控制,最终实现了从几个数十大粒子进行调整的组装大小。我们表明,自限制组装的范围是通过“挫败感逃脱”的两种结构模式来界定的,这些模式逃避了集中曲率的热力学成本。至关重要的是,可以通过合适的选择粘合剂范围和粘附的侧面斑块来抑制这些模式,从而通过形状 - 效率上的形状,结合和胶体构建块的变形性之间的相互作用来提供可行的策略,以编程有限的组装大小。
We show that geometric frustration in a broad class of deformable and naturally curved, shell-like colloidal particles gives rise to self-limiting assembly of finite-sized stacks that far exceed particle dimensions. When inter-particle adhesions favor conformal stacking, particle shape requires {\it curvature focussing} in the stack, leading to a super-extensive accumulation of bending costs that ultimately limit the ground-state stack size to a finite value. Using a combination of continuum theory and particle-based simulation, we demonstrate that the self-limiting stack size is controlled by the ratio of the intra-particle bending costs to inter-particle adhesion energy, ultimately achieving assembly sizes that are tuned from a few, up to several tens of, particles. We show that the range of self-limiting assembly is delimited by the two structural modes of "frustration escape" which evade the thermodynamic costs of curvature focussing. Crucially, each of these modes can be suppressed through suitable choice of adhesive range and lateral patchiness of adhesion, providing feasible strategies to program finite assembly size via the interplay between shape-frustration, binding and deformability of colloidal building blocks.