论文标题

电子 - 音波耦合在激子绝缘子候选ta2nise中的作用5

Role of electron-phonon coupling in excitonic insulator candidate Ta2NiSe5

论文作者

Chen, Cheng, Chen, Xiang, Tang, Weichen, Li, Zhenglu, Wang, Siqi, Ding, Shuhan, Kang, Zhibo, Jozwiak, Chris, Bostwick, Aaron, Rotenberg, Eli, Hashimoto, Makoto, Lu, Donghui, Ruff, Jacob P. C., Louie, Steven G., Birgeneau, Robert, Chen, Yulin, Wang, Yao, He, Yu

论文摘要

电子孔结合对或激子是半导体中的常见激发。当电子孔库仑吸引力超过带隙时,它们可以自发形成并``凝结''进入新的绝缘基态 - 所谓的激子绝缘子。在存在电子偶联的情况下,周期性的晶格失真通常与此激子冷凝物同时发生。然而,电子 - 音波耦合本身也可以引起相似的结构过渡,因此阻碍了基于还原性推理的散装激素绝缘子的清洁识别(例如,哪种不稳定性是相变的“驱动力”)。使用高分辨率同步加速器X射线衍射和角度分辨光发射光谱技术,我们在领先的激子绝缘子候选ta2nise中鉴定了关键的电子 - 光子偶联效应5。其中包括广泛的单向晶格波动和正常状态下的电子伪模,以及电荷掺杂的断裂对称状态的负电子可压缩性。结合第一原理和模型计算,我们确定了一个最小的晶格模型以及捕获实验观测值的相应相互作用参数。更重要的是,我们展示了如何在晶格模型的水平上分离库仑和电子偶联效应,并在研究相关系统的相关系统具有相互交织的订单时,展示了超出还原主义方法的一般框架。

Electron-hole bound pairs, or excitons, are common excitations in semiconductors. They can spontaneously form and ``condense'' into a new insulating ground state -- the so-called excitonic insulator -- when the energy of electron-hole Coulomb attraction exceeds the band gap. In the presence of electron-phonon coupling, a periodic lattice distortion often concomitantly occurs with this exciton condensation. However, similar structural transition can also be induced by electron-phonon coupling itself, therefore hindering the clean identification of bulk excitonic insulators based on reductionistic reasoning (e.g. which instability is the ``driving force'' of the phase transition). Using high-resolution synchrotron x-ray diffraction and angle-resolved photoemission spectroscopy techniques, we identify key electron-phonon coupling effects in a leading excitonic insulator candidate Ta2NiSe5. These include an extensive unidirectional lattice fluctuation and an electronic pseudogap in the normal state, as well as a negative electronic compressibility in the charge-doped broken-symmetry state. In combination with first principles and model calculations, we determine a minimal lattice model and the corresponding interaction parameters that capture the experimental observations. More importantly, we show how the Coulomb and electron-phonon coupling effects can be separated on the level of lattice model, and demonstrate a general framework beyond the reductionist approach in the investigation of correlated systems with intertwined orders.

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