论文标题

量子杂交对无毒卤化物钙钛矿纳米线异质结及其应变控制的负差分电阻

Quantum hybridization negative differential resistance from non-toxic halide perovskite nanowire heterojunctions and its strain control

论文作者

Lee, Juho, Khan, Muhammad Ejaz, Kim, Yong-Hoon

论文摘要

虽然低维有机卤化物钙钛矿有望为各种设备应用打开新的机会,例如在大量对应物中,但基于PB的卤化物钙钛矿材料的毒性是阻碍其实际使用的重大关注点。我们最近预测,铅三碘化物(pbi $ _3 $)列从三甲基硫硫芬(TMS)铅三碘化物(ch $ _3 $)$ _ 3 $ _ 3 $ _ 3 $ _ 3 $ _3 $ _3 $(tmspbi $ _3 $)脱离tms can andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh andrigh nighigh andigh nighigh andigh nigh Arise an由TMSPBI $ _3 $ CHANNED由PBI $ _3 $ electrodes组成的杂项。本文中,我们在计算上探讨了是否可以根据非PB金属元素从其他一维卤化物钙质获得类似的材料和设备特性,并因此加深对其机械起源的理解。首先,通过几个候选金属卤化物无机框架扫描及其父母形成卤化物钙钛矿,我们发现三碘化物(GEI $ _3 $)列还通过避免PEIERLS扭曲来假定具有半金属特征。接下来,采用捆绑的纳米线GEI $ _3 $ -TMSGEI $ _3 $ -GEI $ _3 $连接配置,我们在室温下获得了极高的峰值电流密度和Ultrahigh NDR。此外,揭示了NDR信号在应变下的鲁棒性和可控性,从而确立了其柔性电子应用的潜力。可以强调的是,尽管性能指标明显增强了PBI $ _3 $ -TMSPBI $ _3 $ -PBI $ _3 $案例的指标,但这些设备特性仍然来自相同的量子杂交NDR机制。

While low-dimensional organometal halide perovskites are expected to open up new opportunities for a diverse range of device applications, like in their bulk counterparts, the toxicity of Pb-based halide perovskite materials is a significant concern that hinders their practical use. We recently predicted that lead triiodide (PbI$_3$) columns de-rived from trimethylsulfonium (TMS) lead triiodide (CH$_3$)$_3$SPbI$_3$ (TMSPbI$_3$) by stripping off TMS ligands should be semimetallic, and additionally ultrahigh negative differential resistance (NDR) can arise from the heterojunction composed of a TMSPbI$_3$ channel sandwiched by PbI$_3$ electrodes. Herein, we computationally explore whether similar material and device characteristics can be obtained from other one-dimensional halide perovskites based on non-Pb metal elements, and in doing so deepen the understanding of their mechanistic origins. First, scanning through several candidate metal halide inorganic frameworks as well as their parental form halide perovskites, we find that the germanium triiodide (GeI$_3$) column also assumes a semimetallic character by avoiding the Peierls distortion. Next, adopting the bundled nanowire GeI$_3$-TMSGeI$_3$-GeI$_3$ junction configuration, we obtain a drastically high peak current density and ultrahigh NDR at room temperature. Furthermore, the robustness and controllability of NDR signals under strain are revealed, establishing its potential for flexible electronics applications. It will be emphasized that, despite the performance metrics notably enhanced over those from the PbI$_3$-TMSPbI$_3$-PbI$_3$ case, these device characteristics still arise from the identical quantum hybridization NDR mechanism.

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