论文标题
使异质催化能够实现碳中立性：CO $ _2 $ co $ _2 $的定向催化转化为羧酸
Enabling Heterogeneous Catalysis to Achieve Carbon Neutrality: Directional Catalytic Conversion of CO$_2$ into Carboxylic Acids
论文作者
论文摘要
人为的二氧化碳（CO $ _2 $）的增加加剧了全球环境的恶化，应控制以实现碳中立性。实现碳中立性的核心目标的核心是在经济和可持续条件下使用CO $ _2 $。最近，对碳中立性的强烈需求导致有关Co $ _2 $直接转化为羧酸的直接转化的研究扩散，这可以有效地减轻CO $ _2 $排放并产生高价值化学品。这篇综述的目的是介绍羧酸的应用前景，以及通过光，电和热催化的Co $ _2 $转换为羧酸的基本原理。特别关注的重点是分子水平丰富催化剂活性的调节策略，激发了高性能催化剂的制备。此外，引入了理论计算，高级技术和许多典型示例，以详细说明催化活性的相应过程和影响因素。最后，为该领域的未来发展提供了挑战和前景。希望这篇评论有助于更深入地了解Co $ _2 $转化为羧酸的转换，并激发了更多创新的突破
The increase in anthropogenic carbon dioxide (CO$_2$) emissions has exacerbated the deterioration of the global environment, which should be controlled to achieve carbon neutrality. Central to the core goal of achieving carbon neutrality is the utilization of CO$_2$ under economic and sustainable conditions. Recently, the strong need for carbon neutrality has led to a proliferation of studies on the direct conversion of CO$_2$ into carboxylic acids, which could effectively alleviate CO$_2$ emissions and create high-value chemicals. The purpose of this review is to present the application prospects of carboxylic acids and the basic principles of CO$_2$ conversion into carboxylic acids through photo-, electric-, and thermal catalysis. Special attention is focused on the regulation strategy of the activity of abundant catalysts at the molecular level, inspiring the preparation of high-performance catalysts. In addition, theoretical calculation, advanced technologies, and numerous typical examples are introduced to elaborate on the corresponding process and influencing factors of catalytic activity. Finally, challenges and prospects are provided for the future development of this field. It is hoped that this review contributes to a deeper understanding of the conversion of CO$_2$ into carboxylic acids and inspires more innovative breakthroughs
