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In this paper we propose novel optimization-based methods for verifying reach-avoid (or, eventuality) properties of continuous-time systems modelled by ordinary differential equations. Given a system, an initial set, a safe set and a target set of states, we say that the reach-avoid property holds if for all initial conditions in the initial set, any trajectory of the system starting at them will eventually, i.e.\ in unbounded yet finite time, enter the target set while remaining inside the safe set until that first target hit. Based on a discount value function, two sets of quantified constraints are derived for verifying the reach-avoid property via the computation of exponential/asymptotic guidance-barrier functions (they form a barrier escorting the system to the target set safely at an exponential or asymptotic rate). It is interesting to find that one set of constraints whose solution is termed exponential guidance-barrier functions is just a simplified version of the existing one derived from the moment based method, while the other one whose solution is termed asymptotic guidance-barrier functions is completely new. Furthermore, built upon this new set of constraints, we derive a set of more expressive constraints, which includes the aforementioned two sets of constraints as special instances, providing more chances for verifying the reach-avoid properties successfully. When the involved datum are polynomials, i.e., the initial set, safe set and target set are semi-algebraic, and the system has polynomial dynamics, the problem of solving these sets of constraints can be framed as a semi-definite optimization problem using sum-of-squares decomposition techniques and thus can be efficiently solved in polynomial time via interior point methods. Finally, several examples demonstrate the theoretical developments and performance of proposed methods.