论文标题
高性能真空设备的堆叠导电金属有机框架纳米棒
Stacked conductive metal organic framework nanorods for high performance vacuum electronic devices
论文作者
论文摘要
储层计算是预测湍流的有力工具，其简单的架构具有处理大型系统的计算效率。然而，其实现通常需要完整的状态向量测量和系统非线性知识。我们使用非线性投影函数将系统测量扩展到高维空间，然后将其输入到储层中以获得预测。我们展示了这种储层计算网络在时空混沌系统上的应用，该系统模拟了湍流的若干特征。我们表明，使用径向基函数作为非线性投影器，即使只有部分观测并且不知道控制方程，也能稳健地捕捉复杂的系统非线性。最后，我们表明，当测量稀疏、不完整且带有噪声，甚至控制方程变得不准确时，我们的网络仍然可以产生相当准确的预测，从而为实际湍流系统的无模型预测铺平了道路。
Metal-organic frameworks (MOFs) possessing many unique features have been utilized in several fields in recent years. However, their application in field emission (FE) vacuum electronic device is hindered by their poor electrical conductivity. Herein, a novel conductive MOF of Cu-catecholate (Cu-CAT) with the nanorod length of 200 nm and conductivity of 0.01 S/cm is grown on the graphite paper (GP). Under an applied electric field, a large number of electrons can be emitted from the nanoscale emitter tips of MOF surface to the anode. The great field emission performance of Cu-CAT@GP cold cathode film including a low turn-on field of 0.59e6 V/m and ultra-high field enhancement factor of 29622, even comparable to most carbon-based materials that have been widely investigated in FE studies, is achieved in this work. Meanwhile, Cu-CAT@GP film has a good electrical stability with a current attenuation of 9.4% in two hours. The findings reveal the cathode film fabricated by conductive MOF can be a promising candidate of cold electron source for vacuum electronic applications.
