论文标题
纠缠宏观链或绳索中的宽剪切带的普遍过渡
Universal Transition to Wide Shear Zones in Entangled Macroscale Chains or Ropes
论文作者
论文摘要
已经提出了宏观链,以深入了解分子聚合物系统的物理。然而,了解准二维半合并材料的流变响应,例如珠链包装,目前是一个巨大的挑战。我们在振荡性剪切中研究了宏观链链的随机组合物的非线性流变学 - 包括钢珠链和煮熟的意大利面条。我们表明,在增加应变幅度的情况下,从局部剪切区域进行了普遍的过渡,以增加组成元素的各种长度,灵活性和其他结构参数。临界应变振幅与系统中应变增强发育的发作一致。我们获得了缩放定律,以表明过渡清晰度,剪切区宽度和刚度增强,这是链长的函数。我们的发现表明,在接近临界应变幅度并迅速变长时,组成元素之间的纠缠增强了,甚至跨越了整个有限系统的链条,以足够长的链条。我们表明,非线性流变响应受纠缠导致储存的弹性力增加与剪切速率增加的耗散贡献和链之间互锁的贡献之间的相互作用。
Macroscale chains have been proposed to give insight into the physics of molecular polymer systems. Nevertheless, understanding the rheological response of systems of quasi-one-dimensional semiflexible materials, such as bead-chain packings, is currently a great challenge. We study the nonlinear rheology of random assemblies of macroscale chains -- including steel bead chains and cooked spaghetti -- under oscillatory shear. We show that a universal transition from localized to wide shear zones occurs upon increasing the strain amplitude, for a wide range of lengths, flexibilities, and other structural parameters of the constituent elements. The critical strain amplitude coincides with the onset of strain stiffening development in the system. We obtain scaling laws for transition sharpness, shear-zone width, and stiffness enhancement as a function of chain length. Our findings suggest that the entanglements between the constituent elements strengthen when approaching the critical strain amplitude and rapidly become long range, even spanning the entire finite system for long enough chains. We show that the nonlinear rheological response is governed by the interplay between increasing stored elastic forces due to entanglements and increasing contribution of dissipation with shear rate and interlocking between chains.