论文标题
燃料电池研究中的电池测试方法
Battery Testing Methods in Fuel Cell Research
论文作者
论文摘要
该报告介绍了燃料电池研究中使用的一些关键实验室电化学电池测试方法。伏安法,计时度测定法,计时度计量和电化学阻抗光谱等方法至关重要。所有电化学腐蚀测试均通过包含参考电极,反电极和电解质溶液中的工作电极(金属样品)的三电极极化电池设置进行。所有三个电极均连接到电位静态。金属的腐蚀是通过氧化还原(氧化还原)反应发生的。所有上述测试方法都可以通过操纵电池的电流和电压响应来执行。使用恒定电势在工作电极上进行恒定势并记录电流响应,而速溶实验(计时元素计)则使用恒定电势进行电位实验(伏安法和计时度计),反之亦然。通过所有这些实验进行的测量数据可以提供有关反应可逆性,扩散系数,降低电位,化学反应速率,耐用性,吸附,电压损耗以及对电极材料提供的质量和电荷运输的有效阻力的非常有用的信息。
This report presents some of the key laboratory electrochemical battery testing methods that are used in fuel cell research. Methods such as voltammetry, chronoamperometry, chronopotentiometry, and electrochemical impedance spectroscopy are of major importance. All the electrochemical corrosion tests are performed through a tri-electrode polarization cell setup containing a reference electrode, a counter electrode, and the working electrode (metal sample of interest) in an electrolyte solution. All three electrodes are connected to a potentiostat. Corrosion of metal occurs through an oxidation-reduction (redox) reaction. All the above testing methods can be performed by manipulating the current and voltage responses from the cell. Potentiostatic experiments (voltammetry and chronoamperometry) are performed using constant potential at the working electrode and recording the current response while galvanostatic experiments (chronopotentiometry) and vice versa. The measured data through all these experiments can provide very useful information regarding reaction reversibility, diffusion coefficient, reduction potential, rate of chemical reaction, durability, adsorption, voltage losses, and effective resistance to the mass and charge transport offered by electrode material.