论文标题

薄细胞中铁电列液晶相的介电响应

Dielectric response of a ferroelectric nematic liquid crystalline phase in thin cells

论文作者

Vaupotič, Nataša, Pociecha, Damian, Rybak, Paulina, Matraszek, Joanna, Čepič, Mojca, Wolska, Joanna M., Gorecka, Ewa

论文摘要

我们研究了夹在两个金或ITO电极之间的极性列相(NF)的介电特性,它们用作细胞表面。在批量的情况下,NF有望表现出Goldstone Mode(Phason),因为极化可以均匀旋转而无需能源成本。然而,由于列型导演的方向与极化之间的耦合是有限的,而且即使在没有排列表面层的情况下,限制也会诱导一些能量成本以重新定向极化,因此在KHz方案中,Phason介电弛豫频率也可以测量。 Phason模式很容易被偏置电场淬灭,这使得在甲型化和列列相的阶段都可以遵循极化的波动。这种振幅(软)模式也受边界条件的影响。 NF相中描述相位和振幅波动的理论表明,系统的自由能以及介电响应以极化相关的术语为主导,而柔性电信性仅在非常弱的表面锚固中相关。由于列表弹性术语造成的贡献始终可以忽略不计。该模型将观察到的低频模式与导演波动相关联,与极化波动弱耦合。

We studied dielectric properties of a polar nematic phase (NF) sandwiched between two gold or ITO electrodes, serving as a cell surfaces. In bulk, NF is expected to exhibit a Goldstone mode (phason), because polarization can uniformly rotate with no energy cost. However, because the coupling between the direction of nematic director and polarization is finite, and the confinement, even in the absence of the aligning surface layer, induces some energy cost for a reorientation of polarization, the phason dielectric relaxation frequency is measured in a kHz regime. The phason mode is easily quenched by a bias electric field, which enables fluctuations in the magnitude of polarization to be followed in both, the ferronematic and nematic phases. This amplitude (soft) mode is also influenced by boundary conditions. A theory describing the phase and amplitude fluctuations in the NF phase shows that the free energy of the system and, consequently, the dielectric response are dominated by polarization-related terms with the flexoelectricity being relevant only at a very weak surface anchoring. Contributions due to the nematic elastic terms are always negligible. The model relates the observed low frequency mode to the director fluctuations weakly coupled to polarization fluctuations.

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