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In this paper, we will solve this uniqueness problem of positive solutions to the following equations of exponential growth: \begin{equation*} \begin{cases} -Δu =λue^{u^2},\quad\quad & x\in B_1\subset \mathbb{R}^2,\\ u>0, & x\in B_1,\ \\ u=0,\quad\quad &x\in \partial B_1, \end{cases} \end{equation*} where $ 0<λ<λ_1(B_1)$ and $λ_1(B_1)$ denotes the first eigenvalue of the operator $-Δ$ with the Dirichlet boundary in unit disk. Our method relies on delicate and difficult analysis of radial solutions to the above equation and careful asymptotic expansion of solutions near the boundary. This uniqueness result will shed some light on solving the conjecture that maximizers of the Trudinger-Moser inequality on the unit disc are unique. Furthermore, based on this uniqueness result, we develop a new strategy to establish the quantization property of elliptic equations with the critical exponential growth in the balls of hyperbolic spaces, and obtain the multiplicity and non-existence of positive critical points for super-critical Trudinger-Moser functional. Our method for the quantization property and non-existence of the critical points avoids using the complicated blow-up analysis used in the literature. This method can also be applied to study the similar problems in balls of high dimensional Euclidean space $\mathbb{R}^n$ or hyperbolic spaces provided the uniqueness for the corresponding quasilinear elliptic equations with the critical exponential growth is established.